Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2017-02-15T08:02:02Z | - |
dc.date.available | 2017-02-15T08:02:02Z | - |
dc.date.issued | 2017 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.issn | 1521-3773 | * |
dc.identifier.other | OAK-20075 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/234505 | - |
dc.description.abstract | Redox-inactive metal ions are one of the most important co-factors involved in dioxygen activation and formation reactions by metalloenzymes. In this study, we have shown that the logarithm of the rate constants of electron-transfer and C-H bond activation reactions by nonheme iron(III)-peroxo complexes binding redox-inactive metal ions, [(TMC)Fe-III(O-2)](+)-Mn+ (Mn+=Sc3+, Y3+, Lu3+, and La3+), increases linearly with the increase of the Lewis acidity of the redox-inactive metal ions (Delta E), which is determined from the g(zz) values of EPR spectra of O-2(center dot-)-Mn+ complexes. In contrast, the logarithm of the rate constants of the [(TMC)Fe-III(O-2)](+)-Mn+ complexes in nucleophilic reactions with aldehydes decreases linearly as the Delta E value increases. Thus, the Lewis acidity of the redox-inactive metal ions bound to the mononuclear nonheme iron(III)-peroxo complex modulates the reactivity of the [(TMC)Fe-III(O-2)](+)-Mn+ complexes in electron-transfer, electrophilic, and nucleophilic reactions. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | iron-peroxo intermediates | * |
dc.subject | Lewis acidity | * |
dc.subject | nonheme iron enzymes | * |
dc.subject | reactive species | * |
dc.subject | redox-inactive metal ions | * |
dc.title | Fine Control of the Redox Reactivity of a Nonheme Iron( III)-Peroxo Complex by Binding Redox-Inactive Metal Ions | * |
dc.type | Article | * |
dc.relation.issue | 3 | * |
dc.relation.volume | 56 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 801 | * |
dc.relation.lastpage | 805 | * |
dc.relation.journaltitle | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | * |
dc.identifier.doi | 10.1002/anie.201610828 | * |
dc.identifier.wosid | WOS:000394996900022 | * |
dc.identifier.scopusid | 2-s2.0-85008970146 | * |
dc.author.google | Bae, Seong Hee | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240426135715 | * |