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A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]
- Title
- A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster: [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}]
- Authors
- Kim S.; Kim Y.; Lee J.; Shin W.; Lee M.; Kim S.-J.
- Ewha Authors
- 김성진; 이민영; 김영미
- SCOPUS Author ID
- 김성진; 이민영; 김영미
- Issue Date
- 2007
- Journal Title
- Inorganica Chimica Acta
- ISSN
- 0020-1693
- Citation
- Inorganica Chimica Acta vol. 360, no. 6, pp. 1890 - 1894
- Indexed
- SCI; SCIE; SCOPUS
- Document Type
- Article
- Abstract
- A new layered compound, [MV][{Mn(CH3OH)2}{Re6Se8(CN)6}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV2+ cations (methyl viologen dication = 1,1′-dimethyl-4,4′-bipyridilium dication) reside between the layers. The title compound 1 is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV2+. The MV2+ can be partly exchanged by H2TMB2+ (N,N,N′,N′-tetramethylbenzidine dication) to form a compound [H2TMB2+]x[MV2+]1-x [{Mn(CH3OH)2}{Re6Se8(CN)6}] (2) showing an electronic interaction between the layered framework and [H2TMB]2+ cation. © 2006 Elsevier B.V. All rights reserved.
- DOI
- 10.1016/j.ica.2006.09.028
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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