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First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6-
- Title
- First examples of cyano-bridged complexes based on a novel cluster anion [Re12C17(CN)6]6-
- Authors
- Mironov Yu.V.; Naumov N.G.; Kim S.-J.; Fedorov V.E.
- Ewha Authors
- 김성진
- SCOPUS Author ID
- 김성진
- Issue Date
- 2007
- Journal Title
- Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
- ISSN
- 1070-3284
- Citation
- Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya vol. 33, no. 4, pp. 279 - 285
- Indexed
- SCI; SCIE; SCOPUS
- Document Type
- Article
- Abstract
- Two cyano-bridged compounds of novel dodecanuclear cluster anion [Re 12CS17(CN)6] with Ni2+ cations were synthesized, namely, one-dimensional polymer of the composition [{Ni(NH 3)4} {Ni(NH3)5}2Re 12CS17(CN)6] · 7H2O (I) with a chain structure and [Ni(NH3)6]3[{Ni(NH 3)4}3 {Re12CS17(CN) 6}2] · 21H2O (II), containing the anionic dimeric complex [{Ni(NH3)4}3 {Re 12CS17(CN)6}2]6-. The structures of both compounds were established by X-ray diffraction analysis. Crystals I are monoclinic, space group P2/n, a = 15.321(3), b = 12.635(2), c = 15.448(3) Å, β = 100.242(3)°, V = 2942.8(8) Å3, Z = 2. Crystals II are trigonal, space group R3, a = b = 19.7987(14), c = 28.8642(18) Å, V = 9798.6(12) Å3, Z = 3. © Nauka/Interperiodica 2007.
- DOI
- 10.1134/S1070328407040070
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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