Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2017-01-14T02:01:48Z | - |
dc.date.available | 2017-01-14T02:01:48Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-19962 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/233882 | - |
dc.description.abstract | Photocatalytic enantioselective epoxidation of terminal olefins using a mononuclear non-heme chiral manganese catalyst, [(R,R-BQCN)MnII]2+, and water as an oxygen source yields epoxides with relatively high enantioselectivities (e.g., up to 60% enantiomeric excess). A synthetic mononuclear non-heme chiral Mn(IV)-oxo complex, [(R,R-BQCN)MnIV(O)]2+, affords similar enantioselectivities in the epoxidation of terminal olefins under stoichiometric reaction conditions. Mechanistic details of each individual step of the photoinduced catalysis, including formation of the Mn(IV)-oxo intermediate, are discussed on the basis of combined results of laser flash photolysis and other spectroscopic methods. © 2016 American Chemical Society. | * |
dc.language | English | * |
dc.publisher | American Chemical Society | * |
dc.title | Photocatalytic Asymmetric Epoxidation of Terminal Olefins Using Water as an Oxygen Source in the Presence of a Mononuclear Non-Heme Chiral Manganese Complex | * |
dc.type | Article | * |
dc.relation.issue | 49 | * |
dc.relation.volume | 138 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 15857 | * |
dc.relation.lastpage | 15860 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/jacs.6b10836 | * |
dc.identifier.wosid | WOS:000389962800016 | * |
dc.identifier.scopusid | 2-s2.0-85006256442 | * |
dc.author.google | Shen D. | * |
dc.author.google | Saracini C. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Sun W. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240426135715 | * |