View : 876 Download: 0

Full metadata record

DC Field Value Language
dc.contributor.author남원우*
dc.contributor.authorShunichi Fukuzumi*
dc.contributor.author이용민*
dc.contributor.author정지은*
dc.contributor.authorKei Okubo*
dc.date.accessioned2016-08-29T12:08:10Z-
dc.date.available2016-08-29T12:08:10Z-
dc.date.issued2016*
dc.identifier.issn1433-7851*
dc.identifier.otherOAK-16646*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/231157-
dc.description.abstractReactions of N,N-dimethylaniline (DMA) with nonheme iron(IV)-oxo and iron(IV)-tosylimido complexes occur via different mechanisms, such as an N-demethylation of DMA by a nonheme iron(IV)-oxo complex or an electron transfer dimerization of DMA by a nonheme iron(IV)-tosylimido complex. The change in the reaction mechanism results from the greatly enhanced electron transfer reactivity of the iron(IV)-tosylimido complex, such as the much more positive one-electron reduction potential and the smaller reorganization energy during electron transfer, as compared to the electron transfer properties of the corresponding iron(IV)-oxo complex. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.*
dc.languageEnglish*
dc.publisherWiley-VCH Verlag*
dc.subjectbioinorganic chemistry*
dc.subjectelectron transfer*
dc.subjectiron(IV)-imido complexes*
dc.subjectmechanisms*
dc.subjectN-demethylation*
dc.titleEnhanced Electron Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analogue*
dc.typeArticle*
dc.relation.issue11*
dc.relation.volume55*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage3709*
dc.relation.lastpage3713*
dc.relation.journaltitleAngewandte Chemie - International Edition*
dc.identifier.doi10.1002/anie.201600287*
dc.identifier.wosidWOS:000371521000030*
dc.identifier.scopusid2-s2.0-84975733531*
dc.author.googleVardhaman A.K.*
dc.author.googleLee Y.-M.*
dc.author.googleJung J.*
dc.author.googleOhkubo K.*
dc.author.googleNam W.*
dc.author.googleFukuzumi S.*
dc.contributor.scopusid남원우(7006569723)*
dc.contributor.scopusidShunichi Fukuzumi(35430038100;58409757400)*
dc.contributor.scopusid이용민(36546331100;35233855500;57192113229)*
dc.contributor.scopusid정지은(55320529400)*
dc.contributor.scopusidKei Okubo(7101788990)*
dc.date.modifydate20240130092215*
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

BROWSE