Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | 정지은 | * |
dc.contributor.author | Kei Okubo | * |
dc.date.accessioned | 2016-08-29T12:08:10Z | - |
dc.date.available | 2016-08-29T12:08:10Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.other | OAK-16646 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/231157 | - |
dc.description.abstract | Reactions of N,N-dimethylaniline (DMA) with nonheme iron(IV)-oxo and iron(IV)-tosylimido complexes occur via different mechanisms, such as an N-demethylation of DMA by a nonheme iron(IV)-oxo complex or an electron transfer dimerization of DMA by a nonheme iron(IV)-tosylimido complex. The change in the reaction mechanism results from the greatly enhanced electron transfer reactivity of the iron(IV)-tosylimido complex, such as the much more positive one-electron reduction potential and the smaller reorganization energy during electron transfer, as compared to the electron transfer properties of the corresponding iron(IV)-oxo complex. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | * |
dc.language | English | * |
dc.publisher | Wiley-VCH Verlag | * |
dc.subject | bioinorganic chemistry | * |
dc.subject | electron transfer | * |
dc.subject | iron(IV)-imido complexes | * |
dc.subject | mechanisms | * |
dc.subject | N-demethylation | * |
dc.title | Enhanced Electron Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analogue | * |
dc.type | Article | * |
dc.relation.issue | 11 | * |
dc.relation.volume | 55 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 3709 | * |
dc.relation.lastpage | 3713 | * |
dc.relation.journaltitle | Angewandte Chemie - International Edition | * |
dc.identifier.doi | 10.1002/anie.201600287 | * |
dc.identifier.wosid | WOS:000371521000030 | * |
dc.identifier.scopusid | 2-s2.0-84975733531 | * |
dc.author.google | Vardhaman A.K. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Jung J. | * |
dc.author.google | Ohkubo K. | * |
dc.author.google | Nam W. | * |
dc.author.google | Fukuzumi S. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.contributor.scopusid | 정지은(55320529400) | * |
dc.contributor.scopusid | Kei Okubo(7101788990) | * |
dc.date.modifydate | 20240130092215 | * |