A mononuclear nonheme iron(iii)-peroxo complex binding redox-inactive metal ions

Abstract

Biomimetic compounds; Biomimetic reactions; Electron-transfer reactions; Non-heme iron enzymes; One-electron reductions; Oxidation potentials; Rate determining step; Reorganization energies; Binding energy; Biomimetics; Chemical activation; Electrons; Ionization of gases; Metal complexes; Metal ions; Organometallics; Oxidation; Peroxides; Redox reactions; Reduction; Scandium; Iron compounds