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dc.contributor.author이상기-
dc.contributor.author이준희-
dc.date.accessioned2016-08-28T10:08:06Z-
dc.date.available2016-08-28T10:08:06Z-
dc.date.issued2013-
dc.identifier.issn2041-6520-
dc.identifier.otherOAK-10175-
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/223790-
dc.description.abstractA pair of iridium-catalyzed regiospecific and stereospecific reactions of the carbonates of γ-hydroxy α,β-unsaturated esters were developed. The reaction pathways are strongly affected by the choice of amines employed. A diverse range of γ-substituted α,β-unsaturated γ-amino esters were prepared in excellent yields with various amine nucleophiles such as benzylamine, diallylamine, morpholine, aniline and N-methylaniline. Substitution at the γ-position was well tolerated, encompassing alkyl, aryl and heteroaryl substituents. Enantioenriched (E)-α,β-unsaturated γ-amino esters could also be synthesized from the corresponding enantioenriched allylic carbonates with complete chirality transfer. In sharp contrast, a series of 3,4-disubstituted oxazolidin-2-ones were obtained by using allylamine as a nucleophile. © 2013 The Royal Society of Chemistry.-
dc.languageEnglish-
dc.titleIridium-catalyzed regiospecific and stereospecific allylic amination for the syntheses of α,β-unsaturated γ-amino esters and the bifurcation of the reaction pathway leading to the formation of oxazolidin-2-ones-
dc.typeArticle-
dc.relation.issue7-
dc.relation.volume4-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage2922-
dc.relation.lastpage2927-
dc.relation.journaltitleChemical Science-
dc.identifier.doi10.1039/c3sc50901j-
dc.identifier.wosidWOS:000319940400028-
dc.identifier.scopusid2-s2.0-84878796950-
dc.author.googleLee J.H.-
dc.author.googleLee S.-G.-
dc.contributor.scopusid이상기(15082786300)-
dc.date.modifydate20180104081001-


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