Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2016-08-28T10:08:50Z | - |
dc.date.available | 2016-08-28T10:08:50Z | - |
dc.date.issued | 2012 | * |
dc.identifier.issn | 1434-1948 | * |
dc.identifier.other | OAK-9272 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/223056 | - |
dc.description.abstract | Reaction of a copper(I) complex supported by a sterically demanding tripodal tetradentate ligand, HIPT 3tren, and O 2 gave a mononuclear copper(II) end-on superoxo complex. Spectroscopic (UV/Vis, resonance Raman, ESR, and 1H-NMR) and DFT studies have been performed. The O 2-binding process as well as the reaction toward external substrates have been investigated kinetically to demonstrate the unique behavior of the copper(II) end-on superoxo complex, which may occur as a result of the existence of the hydrophobic core around the copper coordination sphere created by the HIPT 3tren ligand. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | * |
dc.language | English | * |
dc.title | Copper(I)-dioxygen reactivity in a sterically demanding tripodal tetradentate tren ligand: Formation and reactivity of a mononuclear copper(II) end-on superoxo complex | * |
dc.type | Conference Paper | * |
dc.relation.issue | 29 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 4574 | * |
dc.relation.lastpage | 4578 | * |
dc.relation.journaltitle | European Journal of Inorganic Chemistry | * |
dc.identifier.doi | 10.1002/ejic.201200177 | * |
dc.identifier.wosid | WOS:000309467600007 | * |
dc.identifier.scopusid | 2-s2.0-84867055701 | * |
dc.author.google | Kobayashi Y. | * |
dc.author.google | Ohkubo K. | * |
dc.author.google | Nomura T. | * |
dc.author.google | Kubo M. | * |
dc.author.google | Fujieda N. | * |
dc.author.google | Sugimoto H. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Goto K. | * |
dc.author.google | Ogura T. | * |
dc.author.google | Itoh S. | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |