Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.date.accessioned | 2016-08-28T12:08:15Z | - |
dc.date.available | 2016-08-28T12:08:15Z | - |
dc.date.issued | 2012 | * |
dc.identifier.issn | 1070-3284 | * |
dc.identifier.other | OAK-8686 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/222565 | - |
dc.description.abstract | New octahedral anionic heterometal rhenium-osmium cluster complexes [Re 5OsSe 8(OH) 6] 3- and [Re 4Os 2Se 8(OH) 6] 2- were synthesized starting from [Re 5OsSe 8Cl 6] 3- and [Re 4Os 2Se 8Cl 6] 2-, respectively. They were isolated as salts of the compositions Cs 3[Re 5OsSe 8(OH) 6] · 11H 2O (I), K 3[Re 5OsSe 8(OH) 6] · 7H 2O (II), and K 2[Re 4Os 2Se 8(OH) 6] · 3H 2O (III). The protonation of the terminal OH ligands of [Re 5OsSe 8(OH) 6] 3- in an aqueous solution resulted in crystallization of a neutral complex [Re 5OsSe 8(H 2O) 3(OH) 3] · 12H 2O (IV). The compounds have been characterized by single-crystal X-ray diffraction analysis. The luminescence properties of [Re 5OsSe 8(OH) 6] 3- and [Re 4Os 2Se 8(OH) 6] 2- were studied. In addition, the electronic structures of the complexes were elucidated by DFT calculations. © Pleiades Publishing, Ltd., 2012. | * |
dc.language | English | * |
dc.title | Synthesis and structures of new octahedral heterometal rhenium-osmium cluster complexes | * |
dc.type | Article | * |
dc.relation.issue | 3 | * |
dc.relation.volume | 38 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 183 | * |
dc.relation.lastpage | 191 | * |
dc.relation.journaltitle | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya | * |
dc.identifier.doi | 10.1134/S1070328412030025 | * |
dc.identifier.wosid | WOS:000302902500006 | * |
dc.identifier.scopusid | 2-s2.0-84861374994 | * |
dc.author.google | Brylev K.A. | * |
dc.author.google | Naumov N.G. | * |
dc.author.google | Kozlova S.G. | * |
dc.author.google | Ryzhikov M.R. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Kitamura N. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.date.modifydate | 20240301081003 | * |