Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 조재흥 | * |
dc.contributor.author | 이용민 | * |
dc.date.accessioned | 2016-08-28T12:08:06Z | - |
dc.date.available | 2016-08-28T12:08:06Z | - |
dc.date.issued | 2011 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-7862 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/221863 | - |
dc.description.abstract | Mononuclear nonheme iron(IV)-oxo complexes with two different topologies, cis-α-[Fe IV(O)(BQCN)] 2+ and cis-β-[Fe IV(O)(BQCN)] 2+, were synthesized and characterized with various spectroscopic methods. The effect of ligand topology on the reactivities of nonheme iron(IV)-oxo complexes was investigated in C-H bond activation and oxygen atom-transfer reactions; cis-α-[Fe IV(O)(BQCN)] 2+ was more reactive than cis-β-[Fe IV(O)(BQCN)] 2+ in the oxidation reactions. The reactivity difference between the cis-α and cis-β isomers of [Fe IV(O)(BQCN)] 2+ was rationalized with the Fe IV/III redox potentials of the iron(IV)-oxo complexes: the Fe IV/III redox potential of the cis-α isomer was 0.11 V higher than that of the cis-β isomer. © 2011 American Chemical Society. | * |
dc.language | English | * |
dc.title | Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-oxo complex in oxygenation reactions | * |
dc.type | Article | * |
dc.relation.issue | 31 | * |
dc.relation.volume | 133 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 11876 | * |
dc.relation.lastpage | 11879 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/ja204008u | * |
dc.identifier.wosid | WOS:000293768400017 | * |
dc.identifier.scopusid | 2-s2.0-79961131345 | * |
dc.author.google | Hong S. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Cho K.-B. | * |
dc.author.google | Sundaravel K. | * |
dc.author.google | Cho J. | * |
dc.author.google | Kim M.J. | * |
dc.author.google | Shin W. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 조재흥(7403536408) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240426135715 | * |