DSpace at EWHA: A low-spin ruthenium(IV)-oxo complex: Does the spin state have an impact on the reactivity?

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DSpace at EWHA자연과학대학 화학·나노과학전공 Journal papers

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DC Field	Value	Language
dc.contributor.author	Shunichi Fukuzumi	*
dc.date.accessioned	2016-08-28T12:08:52Z	-
dc.date.available	2016-08-28T12:08:52Z	-
dc.date.issued	2010	*
dc.identifier.issn	1433-7851	*
dc.identifier.other	OAK-7042	*
dc.identifier.uri	https://dspace.ewha.ac.kr/handle/2015.oak/221157	-
dc.description.abstract	Spin doesn't matter: A ruthenium(II)-aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven-coordinate low-spin (S=0) ruthenium(IV)-oxo complex (see structure) by oxidation through proton-coupled electron transfer. Comparison of the reactivity of the low-spin and an intermediate-spin (S=1) Ru IV-oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds. © 2010 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim.	*
dc.language	English	*
dc.title	A low-spin ruthenium(IV)-oxo complex: Does the spin state have an impact on the reactivity?	*
dc.type	Article	*
dc.relation.issue	45	*
dc.relation.volume	49	*
dc.relation.index	SCI	*
dc.relation.index	SCIE	*
dc.relation.index	SCOPUS	*
dc.relation.startpage	8449	*
dc.relation.lastpage	8453	*
dc.relation.journaltitle	Angewandte Chemie - International Edition	*
dc.identifier.doi	10.1002/anie.201002733	*
dc.identifier.wosid	WOS:000284015600029	*
dc.identifier.scopusid	2-s2.0-78149428977	*
dc.author.google	Kojima T.	*
dc.author.google	Hirai Y.	*
dc.author.google	Ishizuka T.	*
dc.author.google	Shiota Y.	*
dc.author.google	Yoshizawa K.	*
dc.author.google	Ikemura K.	*
dc.author.google	Ogura T.	*
dc.author.google	Fukuzumi S.	*
dc.contributor.scopusid	Shunichi Fukuzumi(35430038100;58409757400)	*
dc.date.modifydate	20240401081001	*