Manganese(v)-oxo corroles in hydride-transfer reactions

Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E red) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions. © 2010 The Royal Society of Chemistry.