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자연과학대학
화학·나노과학전공
Journal papers
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Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles
Title
Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles
Authors
Kim S.H.
;
Park H.
;
Seo M.S.
;
Kubo M.
;
Ogura T.
;
Klajn J.
;
Gryko D.T.
;
Valentine J.S.
;
Nam W.
Ewha Authors
남원우
;
서미숙
;
Joan S. Valentine
SCOPUS Author ID
남원우
; Joan S. Valentine
Issue Date
2010
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863
Citation
Journal of the American Chemical Society vol. 132, no. 40, pp. 14030 - 14032
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
Mn(IV)-peroxo and Mn(V)-oxo corroles were synthesized and characterized with various spectroscopic techniques. The intermediates were directly used in O-O bond cleavage and formation reactions. Upon addition of proton to the Mn(IV)-peroxo corrole, the formation of the Mn(V)-oxo corrole was observed. Interestingly, addition of base to the Mn(V)-oxo corrole afforded the formation of the Mn(IV)-peroxo corrole. Thus, we were able to report the first example of reversible O-O bond cleavage and formation reactions using in situ generated Mn(IV)-peroxo and Mn(V)-oxo corroles. © 2010 American Chemical Society.
DOI
10.1021/ja1066465
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