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dc.contributor.author남원우*
dc.contributor.authorShunichi Fukuzumi*
dc.contributor.author이용민*
dc.date.accessioned2016-08-28T12:08:34Z-
dc.date.available2016-08-28T12:08:34Z-
dc.date.issued2010*
dc.identifier.issn0002-7863*
dc.identifier.otherOAK-6791*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/220967-
dc.description.abstractIron(III)-superoxo intermediates are believed to play key roles in oxygenation reactions by non-heme iron enzymes. We now report that a non-heme iron(II) complex activates O2 and generates its corresponding iron(IV)-oxo complex in the presence of substrates with weak C-H bonds (e.g., olefins and alkylaromatic compounds). We propose that a putative iron(III)-superoxo intermediate initiates the O2-activation chemistry by abstracting a H atom from the substrate, with subsequent generation of a high-valent iron(IV)-oxo intermediate from the resulting iron(III)-hydroperoxo species. © 2010 American Chemical Society.*
dc.languageEnglish*
dc.titleDioxygen activation by a non-heme iron(II) complex: Formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species*
dc.typeArticle*
dc.relation.issue31*
dc.relation.volume132*
dc.relation.indexSCI*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage10668*
dc.relation.lastpage10670*
dc.relation.journaltitleJournal of the American Chemical Society*
dc.identifier.doi10.1021/ja103903c*
dc.identifier.wosidWOS:000280692200020*
dc.identifier.scopusid2-s2.0-77955401788*
dc.author.googleLee Y.-M.*
dc.author.googleHong S.*
dc.author.googleMorimoto Y.*
dc.author.googleShin W.*
dc.author.googleFukuzumi S.*
dc.author.googleNam W.*
dc.contributor.scopusid남원우(7006569723)*
dc.contributor.scopusidShunichi Fukuzumi(35430038100;58409757400)*
dc.contributor.scopusid이용민(36546331100;35233855500;57192113229)*
dc.date.modifydate20240426135715*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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