DSpace at EWHA: Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

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Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

Title: Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

Authors: Lee Y.M.; Song Y.J.; Poong J.I.; Kim S.H.; Koo H.G.; Lee J.A.; Kim C.; Kim S.-J.; Kim Y.

Ewha Authors: 김성진; 김영미

SCOPUS Author ID: 김성진; 김영미

Issue Date: 2010

Journal Title: Inorganic Chemistry Communications

ISSN: 1387-7003

Citation: Inorganic Chemistry Communications vol. 13, no. 1, pp. 101 - 104

Indexed: SCI; SCIE; SCOPUS

Document Type: Article

Abstract: Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M′(O2CC6H5]n(bpa)n (bpa = 1,2-bis(4-pyridyl)ethane, M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them. © 2009 Elsevier B.V. All rights reserved.