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dc.contributor.author김성진-
dc.contributor.author김영미-
dc.date.accessioned2016-08-28T12:08:23Z-
dc.date.available2016-08-28T12:08:23Z-
dc.date.issued2009-
dc.identifier.issn0959-9428-
dc.identifier.otherOAK-5931-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/220263-
dc.description.abstract[Re6Q8L6]4- (Q = S, Se, Te) clusters can serve as promising "building blocks" for the creation of new porous framworks, nanoparticles and mesoporous materials. Since [Re 6Q8L6]4- clusters have multi-anchoring sites for transition metals, metal-organic complexes, polymers, and multidentated metal complexes, they could be assembled to form various inorganic or organic-inorganic hybrid solids with new various spatial and chemical functions. Because of the controllable architectures and multi-anchoring sites of clusters together with their photoluminescence, rhenium cluster complexes are promising potential candidates as catalysts, chemical color sensors, magnetic materials, gas storage materials, optoelectronic, diagnostic agents, and gene/drug carriers. A new type of mesoscale material comprising [Re6Q8(CN)6]4- and various divalent transition metals in the presence of a liquid crystal template are obtained in 3D cubic, 2D hexagonal, and lamellar phases. The hexahydroxo complexes [Re6Q8(OH)6]4- (Q = S, Se) with high reactivities and a unique rhenium sulfido-cyanide compound, K 8[Re12CS17(CN)6] with a C-centered {Re12} cluster unit were discovered and still many more new rhenium metal cluster complexes at various reaction conditions remain to be explored. © 2009 The Royal Society of Chemistry.-
dc.languageEnglish-
dc.titleNovel compounds based on [Re6Q8(L)6] 4- (Q = S, Se, Te; L = CN, OH) and their applications-
dc.typeArticle-
dc.relation.issue39-
dc.relation.volume19-
dc.relation.indexSCOPUS-
dc.relation.startpage7178-
dc.relation.lastpage7190-
dc.relation.journaltitleJournal of Materials Chemistry-
dc.identifier.doi10.1039/b903929p-
dc.identifier.wosidWOS:000270382400002-
dc.identifier.scopusid2-s2.0-70349832735-
dc.author.googleKim Y.-
dc.author.googleFedorov V.E.-
dc.author.googleKim S.-J.-
dc.contributor.scopusid김성진(34975057300)-
dc.contributor.scopusid김영미(8361744900)-
dc.date.modifydate20201102081004-
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