Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2016-08-28T12:08:18Z | - |
dc.date.available | 2016-08-28T12:08:18Z | - |
dc.date.issued | 2009 | * |
dc.identifier.issn | 0020-1693 | * |
dc.identifier.other | OAK-5818 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/220214 | - |
dc.description.abstract | Five polymeric metal(II)-benzoate complexes of formula [Mn(O2CPh)2(CH3OH)2(bpa)]n (1-Mn), [Co(O2CPh)2(H2O)(bpa)1.5]n (2-Co), [Ni(O2CPh)2(H2O)(bpa)1.5]n (3-Ni), [Cu(O2CPh)2(CH3OH)2(bpa)]n (4-Cu), and [Cd(O2CPh)2(bpa)1.5]n (6-Cd) have been synthesized and characterized (bpa = 1,2-bis(4-pyridyl)ethane). They showed two kinds of structures: parallelogram-like two-dimensional sheets for Co, Ni, and Cd, and one-dimensional chains for Mn, Cu, and Zn. Since similar structures provide similar coordination geometries, the structures depend on the coordination geometries of metal ions. The compounds 1-Mn, 2-Co, 4-Cu, 5-Zn, and 6-Cd have catalyzed efficiently the transesterification of a variety of esters, while 3-Ni has displayed a very slow conversion. The reactivity of catalyst 6-Cd containing Cd ion, well known as an inert metal ion for the ligand substitution, was found to be comparable to that of 5-Zn. The reactivities of the compounds used in this study are in the order of 5-Zn > 6-Cd > 1-Mn > 4-Cu > 2-Co ≫ 3-Ni, indicating that the non-redox metal-containing compounds (5-Zn and 6-Cd) show better activity than the redox-active metal-containing compounds (1-Mn, 4-Cu, 2-Co, and 3-Ni). © 2009 Elsevier B.V. All rights reserved. | * |
dc.language | English | * |
dc.title | Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities | * |
dc.type | Article | * |
dc.relation.issue | 11 | * |
dc.relation.volume | 362 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 4119 | * |
dc.relation.lastpage | 4126 | * |
dc.relation.journaltitle | Inorganica Chimica Acta | * |
dc.identifier.doi | 10.1016/j.ica.2009.06.008 | * |
dc.identifier.wosid | WOS:000268663900034 | * |
dc.identifier.scopusid | 2-s2.0-67849088518 | * |
dc.author.google | Kim S.H. | * |
dc.author.google | Park B.K. | * |
dc.author.google | Song Y.J. | * |
dc.author.google | Yu S.M. | * |
dc.author.google | Koo H.G. | * |
dc.author.google | Kim E.Y. | * |
dc.author.google | Poong J.I. | * |
dc.author.google | Lee J.H. | * |
dc.author.google | Kim C. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Kim Y. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |