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자연과학대학
화학·나노과학전공
Journal papers
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[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand
Title
[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand
Authors
Seo M.S.
;
Kim J.Y.
;
Annaraj J.
;
Kim Y.
;
Lee Y.-M.
;
Kim S.-J.
;
Kim J.
;
Nam W.
Ewha Authors
김성진
;
남원우
;
김영미
;
김진흥
;
이용민
;
서미숙
SCOPUS Author ID
김성진
; 남원우
; 김영미
; 김진흥
; 이용민
Issue Date
2007
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851
Citation
Angewandte Chemie - International Edition vol. 46, no. 3, pp. 377 - 380
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
(Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200603414
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