Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 우애자 | * |
dc.date.accessioned | 2016-08-28T11:08:55Z | - |
dc.date.available | 2016-08-28T11:08:55Z | - |
dc.date.issued | 2002 | * |
dc.identifier.issn | 0897-4756 | * |
dc.identifier.other | OAK-962 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218947 | - |
dc.description.abstract | For quaternary metal thiophosphates, NaNb2PS10, AgNb2PS10, and NaSmP2S6, the principal elements of the 31P NMR chemical shielding tensor (δ11, δ22, δ33) are acquired from the nonlinear least-squares fitting the static powder patterns and MAS spectra. Isotropic chemical shift (δiso) and chemical shielding anisotropy (Δδ) have been employed to correlate with the X-ray crystallographic data, the average (P-S) bond length and the average (S-P-S) bond angle deviation from 109.5°, respectively, at the tetrahedrally coordinated phosphorus atoms. On the basis of these successful correlations, the charge transfer from Na, Ag, and Au metals to the (P-S) ligand is discussed and complemented by the band-structure calculation. | * |
dc.language | English | * |
dc.title | The 31P NMR chemical shielding tensors in quaternary metal thiophosphates, NaNb2PS10, AgNb2PS10, Au0.5Nb2PS10, and NaSmP2S6 | * |
dc.type | Article | * |
dc.relation.issue | 2 | * |
dc.relation.volume | 14 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 518 | * |
dc.relation.lastpage | 523 | * |
dc.relation.journaltitle | Chemistry of Materials | * |
dc.identifier.doi | 10.1021/cm010053v | * |
dc.identifier.wosid | WOS:000173998500011 | * |
dc.identifier.scopusid | 2-s2.0-0036199658 | * |
dc.author.google | Woo A.J. | * |
dc.author.google | Sung-Jin K. | * |
dc.author.google | Park Y.S. | * |
dc.author.google | Eun-Young G. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 우애자(7005894424) | * |
dc.date.modifydate | 20240301081003 | * |