Full metadata record
DC Field | Value | Language |
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dc.contributor.author | 양인상 | - |
dc.date.accessioned | 2016-08-28T11:08:19Z | - |
dc.date.available | 2016-08-28T11:08:19Z | - |
dc.date.issued | 1999 | - |
dc.identifier.issn | 0022-4596 | - |
dc.identifier.other | OAK-306 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218570 | - |
dc.description.abstract | Attempts have been made to prepare various high-Tc superconducting intercalation compounds, M-X-Bi2Sr2Can-1CunO 2n+4+δ (M=metal; X=halogen; n=1, 2, and 3), with the synthetic strategy of hard-soft-acid-base interaction. The chimie douce route such as vapor transport and ionic diffusion is found to be effective in intercalating soft Lewis acidic guest species (I- 3, AgxIx-w w, HgIδ- 2, HgBrδ- 2, and AuIδ- 3) into the Lewis basic Bi2Sr2Can-1CunO 2n+4+δ lattice. According to the X-ray diffraction and magnetic property measurements on these intercalates, it becomes clear that the basal increment upon intercalation (3.25-7.35 Å) is governed by the interlayer geometry of the intercalant, while the accompanying Tc change depends on the charge transfer between host and guest. The extended X-ray absorption fine structure and Raman studies reveal that mercuric halides are intercalated as linear molecules as in vapor state, while silver iodide forms a two-dimensionally extended ionic-conducting channel. In the case of new gold iodide intercalate, unique trigonal planar AuI3 species is identified as the first example of an isolated gold iodide molecule. © 1999 Academic Press. | - |
dc.language | English | - |
dc.title | Heterostructured Bi-Based Cuprate High-Tc Superconductors with Unusually Coordinated Metal Halides | - |
dc.type | Article | - |
dc.relation.issue | 1 | - |
dc.relation.volume | 147 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 328 | - |
dc.relation.lastpage | 335 | - |
dc.relation.journaltitle | Journal of Solid State Chemistry | - |
dc.identifier.doi | 10.1006/jssc.1999.8301 | - |
dc.identifier.wosid | WOS:000083372600041 | - |
dc.identifier.scopusid | 2-s2.0-0001132876 | - |
dc.author.google | Choy J.-H. | - |
dc.author.google | Kim Y.-I. | - |
dc.author.google | Hwang S.-J. | - |
dc.author.google | Yang I.-S. | - |
dc.contributor.scopusid | 양인상(7101797839) | - |
dc.date.modifydate | 20230210140835 | - |