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Synthesis of cyclopenta-fused polycyclic aromatic hydrocarbons utilizing aryl-substituted anilines
- Title
- Synthesis of cyclopenta-fused polycyclic aromatic hydrocarbons utilizing aryl-substituted anilines
- Authors
- Choi, Yeojin; Chatterjee, Tanmay; Kim, Jun; Kim, Jun Soo; Cho, Eun Jin
- Ewha Authors
- 김준수
- SCOPUS Author ID
- 김준수
- Issue Date
- 2016
- Journal Title
- ORGANIC & BIOMOLECULAR CHEMISTRY
- ISSN
- 1477-0520
1477-0539
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY vol. 14, no. 28, pp. 6804 - 6810
- Publisher
- ROYAL SOC CHEMISTRY
- Indexed
- SCIE; SCOPUS
- Document Type
- Article
- Abstract
- Cyclopenta-fused polycyclic aromatic hydrocarbons (CP-PAHs), potentially electronically and biologically highly active materials, were synthesized from readily available 2-aryl-substituted anilines. Reactions occur under extremely mild, room temperature conditions using (BuONO)-Bu-t as the sole reagent. The use of a nitrite source generates a reactive diazonium intermediate in situ that then reacts with a tethered polycyclic aromatic moiety by intramolecular aromatic substitution. This protocol could be presented as one of the simplest methods to access CP-PAHs.
- DOI
- 10.1039/c6ob01235c
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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