Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | Kei Okubo | * |
dc.date.accessioned | 2016-08-27T04:08:59Z | - |
dc.date.available | 2016-08-27T04:08:59Z | - |
dc.date.issued | 2016 | * |
dc.identifier.issn | 1861-4728 | * |
dc.identifier.issn | 1861-471X | * |
dc.identifier.other | OAK-16613 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218097 | - |
dc.description.abstract | Photochlorination of aromatic substrates by hydrogen chloride with 2,3-dichloro-5,6-cyano-p-benzoquinone (DDQ) occurs efficiently to produce the corresponding monochlorinated products selectively under visible-light irradiation. The yields for the chlorination of phenol were 70% and 18% for p- and o-chlorophenol, respectively, without formation of further chlorinated products. The photoinduced chlorination is initiated by electron transfer from Cl- to the triplet excited state of DDQ. The radical intermediates involved in the photochemical reaction have been detected by time-resolved transient absorption measurements. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | chlorination | * |
dc.subject | laser flash photolysis | * |
dc.subject | photoinduced electron transfer | * |
dc.subject | quinone | * |
dc.subject | radical | * |
dc.title | Aromatic Monochlorination Photosensitized by DDQ with Hydrogen Chloride under Visible-Light Irradiation | * |
dc.type | Article | * |
dc.relation.issue | 7 | * |
dc.relation.volume | 11 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 996 | * |
dc.relation.lastpage | 999 | * |
dc.relation.journaltitle | CHEMISTRY-AN ASIAN JOURNAL | * |
dc.identifier.doi | 10.1002/asia.201600083 | * |
dc.identifier.wosid | WOS:000373920600007 | * |
dc.identifier.scopusid | 2-s2.0-84960193854 | * |
dc.author.google | Ohkubo, Kei | * |
dc.author.google | Fujimoto, Atsushi | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | Kei Okubo(7101788990) | * |
dc.date.modifydate | 20240401081001 | * |