Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2016-08-27T04:08:52Z | - |
dc.date.available | 2016-08-27T04:08:52Z | - |
dc.date.issued | 2015 | * |
dc.identifier.issn | 1088-4246 | * |
dc.identifier.issn | 1099-1409 | * |
dc.identifier.other | OAK-16428 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218019 | - |
dc.description.abstract | Using a hydrothermal reaction of SmCl3 center dot 6H(2)O, ZnBr2 and TPPS, a crystalline metalloporphyrinic compound (MPC), [SmZn(TPPS)H3O](n)center dot 2nH(2)O (1), was synthesized. The crystal structure of the MPC exhibits a condensed and robust 3-D porous open framework. We studied the adsorption and desorption isotherms for N-2, H-2 and CO2 conducted at 77 K and 273 K. They show different isotherms such as Type I, II and III isotherm behaviors. We found that low temperature is propitious for the title complex to adsorb more H-2, but less N-2. Compound 1 showed remarkably high selectivity for CO2-N-2 separation, and good thermal stability. The temperature dependent magnetic susceptibility shows an antiferromagnetic-like behavior for 1. | * |
dc.language | English | * |
dc.publisher | WORLD SCI PUBL CO INC | * |
dc.subject | crystal | * |
dc.subject | lanthanide | * |
dc.subject | photoluminescence | * |
dc.subject | porphyrin | * |
dc.subject | zinc | * |
dc.title | A metalloporphyrinic compound with a high selectivity for N-2 and CO2 separation | * |
dc.type | Article | * |
dc.relation.issue | 12 | * |
dc.relation.volume | 19 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 1225 | * |
dc.relation.lastpage | 1231 | * |
dc.relation.journaltitle | JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | * |
dc.identifier.doi | 10.1142/S1088424615501102 | * |
dc.identifier.wosid | WOS:000370297900002 | * |
dc.identifier.scopusid | 2-s2.0-84957560639 | * |
dc.author.google | Zhang, Xian | * |
dc.author.google | Chen, Wen-Tong | * |
dc.author.google | Suenobu, Tomoyoshi | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Wang, Ming-Sheng | * |
dc.author.google | Guo, Guo-Cong | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240130092215 | * |