View : 727 Download: 0

Full metadata record

DC Field Value Language
dc.contributor.authorShunichi Fukuzumi*
dc.date.accessioned2016-08-27T04:08:52Z-
dc.date.available2016-08-27T04:08:52Z-
dc.date.issued2015*
dc.identifier.issn1088-4246*
dc.identifier.issn1099-1409*
dc.identifier.otherOAK-16428*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/218019-
dc.description.abstractUsing a hydrothermal reaction of SmCl3 center dot 6H(2)O, ZnBr2 and TPPS, a crystalline metalloporphyrinic compound (MPC), [SmZn(TPPS)H3O](n)center dot 2nH(2)O (1), was synthesized. The crystal structure of the MPC exhibits a condensed and robust 3-D porous open framework. We studied the adsorption and desorption isotherms for N-2, H-2 and CO2 conducted at 77 K and 273 K. They show different isotherms such as Type I, II and III isotherm behaviors. We found that low temperature is propitious for the title complex to adsorb more H-2, but less N-2. Compound 1 showed remarkably high selectivity for CO2-N-2 separation, and good thermal stability. The temperature dependent magnetic susceptibility shows an antiferromagnetic-like behavior for 1.*
dc.languageEnglish*
dc.publisherWORLD SCI PUBL CO INC*
dc.subjectcrystal*
dc.subjectlanthanide*
dc.subjectphotoluminescence*
dc.subjectporphyrin*
dc.subjectzinc*
dc.titleA metalloporphyrinic compound with a high selectivity for N-2 and CO2 separation*
dc.typeArticle*
dc.relation.issue12*
dc.relation.volume19*
dc.relation.indexSCI*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage1225*
dc.relation.lastpage1231*
dc.relation.journaltitleJOURNAL OF PORPHYRINS AND PHTHALOCYANINES*
dc.identifier.doi10.1142/S1088424615501102*
dc.identifier.wosidWOS:000370297900002*
dc.identifier.scopusid2-s2.0-84957560639*
dc.author.googleZhang, Xian*
dc.author.googleChen, Wen-Tong*
dc.author.googleSuenobu, Tomoyoshi*
dc.author.googleFukuzumi, Shunichi*
dc.author.googleWang, Ming-Sheng*
dc.author.googleGuo, Guo-Cong*
dc.contributor.scopusidShunichi Fukuzumi(35430038100;58409757400)*
dc.date.modifydate20240130092215*
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

BROWSE