Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | 정지은 | * |
dc.contributor.author | Kei Okubo | * |
dc.date.accessioned | 2016-08-27T04:08:12Z | - |
dc.date.available | 2016-08-27T04:08:12Z | - |
dc.date.issued | 2015 | * |
dc.identifier.issn | 0020-1669 | * |
dc.identifier.issn | 1520-510X | * |
dc.identifier.other | OAK-15695 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/217643 | - |
dc.description.abstract | Rate constants of electron self-exchange of high-valent oxo and imido complexes of chromium(V/IV) corrole have been determined in acetonitrile and toluene at various temperatures by electron paramagnetic resonance (EPR) line width variation of the EPR spectra. The observed activation enthalpies (Delta H-obs double dagger) of electron self-exchange of chromium(V)-oxo and -imido corrole with the corresponding chromium(IV) complexes are zero in toluene, whereas the Delta H-obs double dagger values are slightly positive in acetonitrile. Such activationless electron self-exchange transfer resulted in extremely fast electron-transfer reactions of chromium(V)-oxo and -imido corrole in sharp contrast with slow electron-transfer reactions of other high-valent metal-oxo and -imido complexes. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Activationless Electron Self-Exchange of High-Valent Oxo and Imido Complexes of Chromium Corroles | * |
dc.type | Article | * |
dc.relation.issue | 18 | * |
dc.relation.volume | 54 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 9223 | * |
dc.relation.lastpage | 9228 | * |
dc.relation.journaltitle | INORGANIC CHEMISTRY | * |
dc.identifier.doi | 10.1021/acs.inorgchem.5b01777 | * |
dc.identifier.wosid | WOS:000361865600047 | * |
dc.identifier.scopusid | 2-s2.0-84942134621 | * |
dc.author.google | Liu, Shuo | * |
dc.author.google | Jung, Jieun | * |
dc.author.google | Ohkubo, Kei | * |
dc.author.google | Hicks, Scott D. | * |
dc.author.google | Bougher, Curt J. | * |
dc.author.google | Abu-Omar, Mandi M. | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 정지은(55320529400) | * |
dc.contributor.scopusid | Kei Okubo(7101788990) | * |
dc.date.modifydate | 20240401081001 | * |