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dc.contributor.author남원우-
dc.contributor.author이용민-
dc.contributor.author서미숙-
dc.date.accessioned2016-08-27T04:08:58Z-
dc.date.available2016-08-27T04:08:58Z-
dc.date.issued2015-
dc.identifier.issn1433-7851-
dc.identifier.issn1521-3773-
dc.identifier.otherOAK-15474-
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/217505-
dc.description.abstractHigh-spin iron(III)-iodosylarene complexes are highly reactive in the epoxidation of olefins, in which epoxides are formed as the major products with high stereospecificity and enantioselectivity. The reactivity of the iron(III)-iodosylarene intermediates is much greater than that of the corresponding iron(IV)-oxo complex in these reactions. The iron(III)-iodosylarene species-not high-valent iron(IV)-oxo and iron(V)-oxo species-are also shown to be the active oxidants in catalytic olefin epoxidation reactions. The present results are discussed in light of the long-standing controversy on the one oxidant versus multiple oxidants hypothesis in oxidation reactions.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectbioinorganic chemistry-
dc.subjectenzyme models-
dc.subjectepoxidation-
dc.subjectiron complexes-
dc.subjectreaction mechanisms-
dc.titleMononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions-
dc.typeArticle-
dc.relation.issue40-
dc.relation.volume54-
dc.relation.indexSCI-
dc.relation.indexSCIE-
dc.relation.indexSCOPUS-
dc.relation.startpage11740-
dc.relation.lastpage11744-
dc.relation.journaltitleANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.201505796-
dc.identifier.wosidWOS:000363394800024-
dc.identifier.scopusid2-s2.0-84942295578-
dc.author.googleWang, Bin-
dc.author.googleLee, Yong-Min-
dc.author.googleSeo, Mi Sook-
dc.author.googleNam, Wonwoo-
dc.contributor.scopusid남원우(7006569723)-
dc.contributor.scopusid이용민(36546331100;35233855500)-
dc.contributor.scopusid서미숙(7101805112)-
dc.date.modifydate20210708143921-
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자연과학대학 > 화학·나노과학전공 > Journal papers
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