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dc.contributor.authorShunichi Fukuzumi*
dc.date.accessioned2016-08-27T04:08:25Z-
dc.date.available2016-08-27T04:08:25Z-
dc.date.issued2015*
dc.identifier.issn0002-7863*
dc.identifier.otherOAK-14834*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/217157-
dc.description.abstractThe visible light-driven, catalytic aerobic oxidation of benzylic C-H bonds was mediated by a Mn-III corrolazine complex. To achieve catalytic turnovers, a strict selective requirement for the addition of protons was established. The resting state of the catalyst was unambiguously characterized by X-ray diffraction as [Mn-III((HO)-O-2)(TBP(8)Cz(H))](+), in which a single, remote site on the ligand is protonated. If two remote sites are protonated, however, reactivity with O-2 is shut down. Spectroscopic methods revealed that the related Mn-V(O) complex is also protonated at the same remote site at -60 degrees C, but undergoes valence tautomerization upon warming.*
dc.languageEnglish*
dc.publisherAMER CHEMICAL SOC*
dc.titleLight-Driven, Proton-Controlled, Catalytic Aerobic C-H Oxidation Mediated by a Mn(III) Porphyrinoid Complex*
dc.typeArticle*
dc.relation.issue14*
dc.relation.volume137*
dc.relation.indexSCI*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage4614*
dc.relation.lastpage4617*
dc.relation.journaltitleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY*
dc.identifier.doi10.1021/jacs.5b00816*
dc.identifier.wosidWOS:000353177100006*
dc.identifier.scopusid2-s2.0-84927927274*
dc.author.googleNeu, Heather M.*
dc.author.googleJung, Jieun*
dc.author.googleBaglia, Regina A.*
dc.author.googleSiegler, Maxime A.*
dc.author.googleOhkubo, Kei*
dc.author.googleFukuzumi, Shunichi*
dc.author.googleGoldberg, David P.*
dc.contributor.scopusidShunichi Fukuzumi(35430038100;57375583300)*
dc.date.modifydate20220813081001*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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