Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2016-08-27T04:08:25Z | - |
dc.date.available | 2016-08-27T04:08:25Z | - |
dc.date.issued | 2015 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-14834 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/217157 | - |
dc.description.abstract | The visible light-driven, catalytic aerobic oxidation of benzylic C-H bonds was mediated by a Mn-III corrolazine complex. To achieve catalytic turnovers, a strict selective requirement for the addition of protons was established. The resting state of the catalyst was unambiguously characterized by X-ray diffraction as [Mn-III((HO)-O-2)(TBP(8)Cz(H))](+), in which a single, remote site on the ligand is protonated. If two remote sites are protonated, however, reactivity with O-2 is shut down. Spectroscopic methods revealed that the related Mn-V(O) complex is also protonated at the same remote site at -60 degrees C, but undergoes valence tautomerization upon warming. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Light-Driven, Proton-Controlled, Catalytic Aerobic C-H Oxidation Mediated by a Mn(III) Porphyrinoid Complex | * |
dc.type | Article | * |
dc.relation.issue | 14 | * |
dc.relation.volume | 137 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 4614 | * |
dc.relation.lastpage | 4617 | * |
dc.relation.journaltitle | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | * |
dc.identifier.doi | 10.1021/jacs.5b00816 | * |
dc.identifier.wosid | WOS:000353177100006 | * |
dc.identifier.scopusid | 2-s2.0-84927927274 | * |
dc.author.google | Neu, Heather M. | * |
dc.author.google | Jung, Jieun | * |
dc.author.google | Baglia, Regina A. | * |
dc.author.google | Siegler, Maxime A. | * |
dc.author.google | Ohkubo, Kei | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Goldberg, David P. | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240130092215 | * |