Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 박준우 | - |
dc.date.accessioned | 2016-08-27T02:08:37Z | - |
dc.date.available | 2016-08-27T02:08:37Z | - |
dc.date.issued | 2001 | - |
dc.identifier.issn | 1472-779X | - |
dc.identifier.other | OAK-883 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/215460 | - |
dc.description.abstract | beta -Cyclodextrin (beta -CDx) derivatives modified with p-xylylenediamine at the 3-position, mono-3-deoxy-3-[4-(aminomethyl)benzylamino]-beta -CDx (1; beta -CDx-3-p-xylylenediamine) was prepared by the reaction of beta -CDx-2,3-manno-epoxide with p-xylylenediamine. The circular dichroism properties of 1 are compared with those of the corresponding beta -CDx derivative modified at the primary side (2; beta -CDx-6-p-xylylenediamine), in the presence and in the absence of 1-adamantanamine . HCl. The results indicate that the xylylenediamine group of 2 is self-included in the beta -CDx cavity, whereas that of 1 stays outside the cavity. The energy obtained by molecular modeling showed the same trend. The dependence of self-inclusion behavior of a pendant group in modified cyclodextrins on the position of modification could be a useful guide for designing cyclodextrin derivatives for various applications. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Preparation and self-inclusion properties of p-xylylenediamine-modified beta-cyclodextrins: dependence on the side of modification | - |
dc.type | Article | - |
dc.relation.issue | 11 | - |
dc.relation.index | SCIE | - |
dc.relation.startpage | 2114 | - |
dc.relation.lastpage | 2118 | - |
dc.relation.journaltitle | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | - |
dc.identifier.doi | 10.1039/b105388b | - |
dc.identifier.wosid | WOS:000172200000012 | - |
dc.author.google | Park, KK | - |
dc.author.google | Kim, YS | - |
dc.author.google | Lee, SY | - |
dc.author.google | Song, HE | - |
dc.author.google | Park, JW | - |
dc.contributor.scopusid | 박준우(35332923800) | - |
dc.date.modifydate | 20220119160750 | - |