Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.date.accessioned | 2016-08-27T02:08:22Z | - |
dc.date.available | 2016-08-27T02:08:22Z | - |
dc.date.issued | 1999 | * |
dc.identifier.issn | 0020-1669 | * |
dc.identifier.other | OAK-240 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/215306 | - |
dc.description.abstract | An iron(III) porphyrin complex with highly electron-withdrawing substituents on the porphyrin ligand efficiently catalyzes the hydroxylation of alkanes by H2O2 via enzyme mimetic oxidation reactions in aprotic solvent. An "isolated" high-valent iron(IV) oxo porphyrin cation radical intermediate, prepared in situ by reaction of the iron porphyrin complex with m-CPBA at -40 degrees C, is capable of activating C-H bonds of alkanes to give oxygenated products efficiently. The hydroxylating intermediate generated in the catalytic H2O2 reaction is evidenced to be the high-valent iron(IV) oxo porphyrin cation radical species. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Biomimetic alkane hydroxylations by an iron(III) porphyrin complex with H2O2 and by a high-valent iron(IV) oxo porphyrin cation radical complex | * |
dc.type | Article | * |
dc.relation.issue | 13 | * |
dc.relation.volume | 38 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 3238 | * |
dc.relation.lastpage | + | * |
dc.relation.journaltitle | INORGANIC CHEMISTRY | * |
dc.identifier.doi | 10.1021/ic980670u | * |
dc.identifier.wosid | WOS:000081189300033 | * |
dc.identifier.scopusid | 2-s2.0-0001606867 | * |
dc.author.google | Nam, W | * |
dc.author.google | Goh, YM | * |
dc.author.google | Lee, YJ | * |
dc.author.google | Lim, MH | * |
dc.author.google | Kim, C | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.date.modifydate | 20240116111857 | * |