Browsing byAuthorUm, Ik-Hwan

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Showing results 1 to 17 of 17

Issue DateTitleAuthor(s)Type
2017Alkali metal ion catalysis and inhibition in alkaline ethanolysis of O-Y-substituted-phenyl O-phenyl thionocarbonates: contrasting M+ ion effects upon changing electrophilic centre from C=O to C=S엄익환Article
2015Evidence for a Catalytic Six-Membered Cyclic Transition State in Aminolysis of 4-Nitrophenyl 3,5-Dinitrobenzoate in Acetonitrile: Comparative Bronsted-Type Plot, Entropy of Activation, and Deuterium Kinetic Isotope Effects엄익환Article
2019Hydrazinolysis of aryl cinnamates and related esters: the alpha-effect arises from stabilization of five-membered cyclic transition state엄익환Article
2014Kinetic Study on Aminolysis of 4-Nitrophenyl Isonicotinate in Acetonitrile: Effect of Amine Basicity on Reactivity and Reaction Mechanism엄익환Article
2016Kinetic Study on Aminolysis of 4-Pyridyl Benzoate and O-4-Pyridyl Thionobenzoate in Acetonitrile: Factors Influencing Reactivity and Reaction Mechanism엄익환Article
2019Kinetic study on aminolysis of aryl X-substituted-cinnamates in acetonitrile: differential medium effect determines reactivity and reaction mechanism엄익환Article
2016Kinetic Study on Aminolysis of O-2-Pyridyl Thionobenzoate in Acetonitrile: Effect of Changing Electrophilic Center from C=O to C=S on Reactivity and Reaction Mechanism엄익환Article
2014Kinetic Study on Aminolysis of Phenyl 2-Pyridyl Carbonate in Acetonitrile: Effect of Intramolecular H-bonding Interaction on Reactivity and Reaction Mechanism엄익환Article
2016Kinetic Study on Nucleophilic Displacement Reactions of Phenyl Y-Substituted Phenyl Carbonates with 1,8-Diazabicyclo[5.4.0]undec-7-ene: Effects of Amine Nature on Reaction Mechanism엄익환Article
2016Kinetic Study on Nucleophilic Substitution Reactions of Aryl Diphenylphosphinates with Butane-2,3-dione Monoximate and Aryloxide Anions: Reaction Mechanism and Origin of the -Effect엄익환Article
2015Kinetic Study on Reactions of O-Y-substituted Phenyl Thionobenzoates with Quinuclidine: Factors Governing Reactivity and Reaction Mechanism엄익환Article
2014Kinetic Study on SNAr Reaction of 1-Y-Substituted-phenoxy-2,4-dinitrobenzenes with Hydroxide Ion: Effect of Substituent Y on Reactivity and Reaction Mechanism엄익환Article
2018Medium effect on the alpha-effect for nucleophilic substitution reactions of p-nitrophenyl acetate with benzohydroxamates and m-chlorophenoxide in DMSO-H2O mixtures as contrasts with MeCN-H2O mixtures: comparing two very different polar aprotic solvent components엄익환Article
2017Multiparameter kinetic analysis of alkaline hydrolysis of a series of aryl diphenylphosphinothioates: models for P=S neurotoxins엄익환Article
2008Reaction Mechanism and Structure of Transition State Determined from Analysis of Bronsted beta(nuc) for Aminolysis of 4-Nitrophenyl Diphenylphosphinate엄익환Article
2015The alpha-effect in the SNAr reaction of 1-(4-nitrophenoxy)-2,4-dinitrobenzene with anionic nucleophiles: effects of solvation and polarizability on the alpha-effect엄익환Article
2018Unexpected medium effect on the mechanism for aminolysis of aryl phenyl carbonates in acetonitrile and H2O: transition-state structure in the catalytic pathway엄익환Article

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