Browsing byAuthorBuncel E.

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Showing results 1 to 16 of 16

Issue DateTitleAuthor(s)Type
2013A kinetic study on nucleophilic displacement reactions of aryl benzenesulfonates with potassium ethoxide: Role of K+ ion and reaction mechanism deduced from analyses of LFERs and activation parameters엄익환Article
2008Alkali metal ion catalysis and inhibition in nucleophilic displacement reactions at phosphorus centers: Ethyl and methyl paraoxon and ethyl and methyl parathion엄익환Article
2014Alkali-metal ion catalysis and inhibition in SNAr displacement: Relative stabilization of ground state and transition state determines catalysis and inhibition in SNAr reactivity엄익환Article
2012Alkali-metal-ion catalysis and inhibition in the nucleophilic displacement reaction of Y-substituted phenyl diphenylphosphinates and diphenylphosphinothioates with alkali-metal ethoxides: effect of changing the electrophilic center from P=O to P=S엄익환Article
2013Dissection of activation parameters in the bell-shaped α-effect following solvent modulation (DMSO-H2O Media)엄익환Article
2005Effect of modification of the electrophilic center on the α effect엄익환Article
2009Effects on the reactivity by changing the electrophilic center from C=O to C=S: Contrasting reactivity of hydroxide, p-chlorophenoxide, and butan-2,3-dione monoximate in DMSO/H2O mixtures엄익환Article
2001Ground-state versus transition-state effects on the α-effect as expressed by solvent effects [24]엄익환Letter
2006Medium effects on the α-effect in DMSO-H2O mixtures - Comparative studies of p-nitrophenyl benzoate and acetate - Dissection of ground-state and transition-state effects엄익환Article
2010Pitfalls in assessing the α-effect: Reactions of substituted phenyl methanesulfonates with HOO-, OH-, and substituted phenoxides in H2O엄익환Article
2002Reinterpretation of curved hammett plots in reaction of nucleophiles with aryl benzoates: Change in rate-determining step or mechanism versus ground-state stabilization엄익환Article
2001Solvent effect on the α-effect for the reactions of aryl acetates with butane-2,3-dione monoximate and p-chlorophenoxide in MeCN-H2O mixtures엄익환Article
2006Solvent effect on the α-effect: Ground-state versus transition-state effects; a combined calorimetric and kinetic investigation엄익환Article
2001The effect of solvent on the α-effect: C=O, P=O and SO2 centers엄익환Article
2000The origin of the α-effect: Dissection of ground-state and transition- state contributions엄익환Article
2004The α-effect and its modulation by solvent엄익환Article

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