Metal-organic frameworks for high-performance cathodes in batteries

Abstract

Metal-organic frameworks (MOFs) are functional materials that are proving to be indispensable for the development of next-generation batteries. The porosity, crystallinity, and abundance of active sites in MOFs, which can be tuned by selecting the appropriate transition metal/organic linker combination, enable MOFs to meet the performance requirements for cathode materials in batteries. Recent studies on the use of MOFs in cathodes have verified their high durability, cyclability, and capacity thus demonstrating the huge potential of MOFs as high-performance cathode materials. However, to keep pace with the rapid growth of the battery industry, several challenges hindering the development of MOF-based cathode materials need to be overcome. This review analyzes current applications of MOFs to commercially available lithium-ion batteries as well as advanced batteries still in the research stage. This review provides a comprehensive outlook on the progress and potential of MOF cathodes in meeting the performance requirements of the future battery industry. © 2024 The Authors