Economic and environmental insights into the hybrid ethylene oxide production processes

Abstract

The electrochemical reduction of CO2 into petrochemical precursors is a promising sustainable technology that has the potential to replace conventional processes which utilize fossil fuels. However, compared to primary precursors which are generally analyzed through integrated techno-economic analysis and life-cycle assessment, research on crucial secondary precursors, such as ethylene oxide, is relatively limited. Here, we conducted holistic economic and environmental evaluation for nine potential ethylene oxide production pathways with either CO2 or ethane as the main feed source and compared the profitability and environmental effects of different process alignments. To achieve this, we designed unit processes and combined them to establish pathways for ethylene oxide production. In addition to techno-economic and life cycle analysis, sensitivity analysis was also performed to determine the most important electrochemical parameters, which were identified as the current density and Faradaic efficiency. Finally, we evaluated the influence of carbon credits in relation to target carbon reductions based on stated guidelines for future economic planning. Collectively, the results indicated that the techno-economic feasibility of ethylene oxide production pathways was strongly associated with the feed sources and process configurations. This work demonstrates that conventional ethylene oxide production can be replaced by a more profitable and environmentally-friendly alternative based on combining conventional and electrochemical processes. © 2024 Elsevier B.V.