Facile fabrication and grain-size depended on structural behavior of Cadmium-Substituted nano Co-Ni ferrites by chemical method

Abstract

In this work, cadmium doped cobalt nickel ferrites were fabricated via co-precipitation method by using high purity chlorides as precursors and ammonia as precipitate. XRD measurements of synthesized Co0.6Ni0.4-xCdxFe2O4 ferrite samples revealed that the formation of mono phase cubic spinel structure ferrite nanoparticles. The volume of unit cell, crystallite size, lattice constant, bond length, hopping length, ionic radii and microstrain were directly affected by the inclusion of Cd2+ content in Co-Ni ferrite. The crystallite size (Dxrd) of prepared ferrite samples was obtained in between 14.52 and 16.92 nm. FTIR spectra showed two main absorption bands in the frequency range of 400–600 cm−1 arising due to stretching vibrations of tetrahedral (A) and octahedral (B) sites respectively. SEM analysis showed agglomerated morphology of ferrite nanoparticles with grain size decreased from 0.85 to 0.21 μm. Raman spectroscopy confirmed that, on addition of Cd2+content, Raman band was shifted towards higher wave number side. The crystallite development in Cd doped Co-Ni ferrites was explored by X-ray peak broadening methods such as Scherer's formula, Size-Strain plot and Williamson hall methods. XRD analysis confirmed, the crystallite size and microstrain of Co0.6Ni0.4-xCdxFe2O4 ferrites were obtained from various methods, are highly inter correlated. Saturation magnetization (Ms) was decreased from 29.92 to 23.40 emu/gm with increase of Cd doping. The coercivity was reduced from 1113 to 708 Oe with Cd concentration. This is due to the magnetic anisotropy constant of Ni2+ ion is higher than that of the Cd2+ ion. © 2023 THE AUTHORS