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Design, Synthesis, and Applications of a Vanadium Complex: An Effective Catalyst for the Direct Conversion of Alcohols and Aldehydes to Esters
- Title
- Design, Synthesis, and Applications of a Vanadium Complex: An Effective Catalyst for the Direct Conversion of Alcohols and Aldehydes to Esters
- Authors
- Mali G.; Verma I.; Arora H.; Rajput A.; Kumar A.; Erande R.D.
- Ewha Authors
- Akhilesh Kumar
- SCOPUS Author ID
- Akhilesh Kumar
- Issue Date
- 2023
- Journal Title
- Journal of Organic Chemistry
- ISSN
- 0022-3263
- Citation
- Journal of Organic Chemistry vol. 88, no. 9, pp. 5696 - 5703
- Publisher
- American Chemical Society
- Indexed
- SCIE; SCOPUS
- Document Type
- Article
- Abstract
- A novel bench-stable V-catalyst [(L2)VIVO](ClO4) was synthesized and characterized by X-ray diffraction (XRD) analysis and FT-IR, UV-visible, and EPR spectroscopies, which confirmed its excellent catalytic activity. In application, aldehydes are rapidly converted into their corresponding esters without additives in a one-pot manner using a newly developed catalyst [(L2)VIVO](ClO4) and H2O2 as a green oxidant. The developed method is compatible with a broad range of densely substituted aldehydes and allows for the facile preparation of aliphatic, aromatic, and heterocyclic esters, including esters derived from CD3OD, methanol, ethanol, iso-propanol, n-butanol, sec-butyl alcohol, and propargylic alcohol. Gratifyingly, numerous alcohols also directly converted to their corresponding esters in a one-pot manner. We disclose herein the direct conversion of two different functionalities (alcohols and aldehydes) into esters (33 examples) with satisfactory yields, showing the potential of the developed catalyst toward varied oxidative organic transformations in a one-pot manner. © 2023 American Chemical Society.
- DOI
- 10.1021/acs.joc.3c00159
- Appears in Collections:
- 연구기관 > 나노바이오·에너지소재센터 > Journal papers
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