Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유영민 | * |
dc.date.accessioned | 2022-08-12T16:31:20Z | - |
dc.date.available | 2022-08-12T16:31:20Z | - |
dc.date.issued | 2022 | * |
dc.identifier.issn | 1463-9262 | * |
dc.identifier.issn | 1463-9270 | * |
dc.identifier.other | OAK-32118 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/262402 | - |
dc.description.abstract | A distinctive sustainable approach has been developed to afford highly functionalized CF3-hydroquinone derivatives as potent biologically active molecules. The synthetic protocol involves the photoirradiation of a mixture of easily accessible benzoquinones and CF3SO2Na. This process generates a quinhydrone charge-transfer complex of benzoquinone and its in situ generated hydroquinone in the presence of a small amount of hydrogen donors, more preferably water. The subsequent formation of a transient ternary complex involving CF3SO2Na elicits photoinduced charge-transfer (CT), thereby producing CF3-hydroquinones. The present method is highly practical and atom-economical whilst avoiding the use of any sacrificial electron donors. Furthermore, the unique ternary complex intermediate permits site-selective three-component trifluoromethylation in the presence of vinyl arenes. | * |
dc.language | English | * |
dc.publisher | ROYAL SOC CHEMISTRY | * |
dc.title | Sustainable photoredox chemistry of a transient ternary complex: an unconventional approach toward trifluoromethylated hydroquinones | * |
dc.type | Article | * |
dc.relation.issue | 17 | * |
dc.relation.volume | 24 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 6481 | * |
dc.relation.lastpage | 6486 | * |
dc.relation.journaltitle | GREEN CHEMISTRY | * |
dc.identifier.doi | 10.1039/d2gc01691e | * |
dc.identifier.wosid | WOS:000813556900001 | * |
dc.identifier.scopusid | 2-s2.0-85132724305 | * |
dc.author.google | Lee, Da Seul | * |
dc.author.google | Soni, Vineet Kumar | * |
dc.author.google | Heo, Seunga | * |
dc.author.google | Hwang, Ho Seong | * |
dc.author.google | You, Youngmin | * |
dc.author.google | Cho, Eun Jin | * |
dc.contributor.scopusid | 유영민(24759463600) | * |
dc.date.modifydate | 20240422132144 | * |