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Green-Light-Driven Fe(III)(btz)(3) Photocatalysis in the Radical Cationic [4+2] Cycloaddition Reaction
- Title
- Green-Light-Driven Fe(III)(btz)(3) Photocatalysis in the Radical Cationic [4+2] Cycloaddition Reaction
- Authors
- Jang, Yu Jeong; An, Hyeju; Choi, Seunghee; Hong, Jayeon; Lee, Seung Hyun; Ahn, Kwang-Hyun; You, Youngmin; Kang, Eun Joo
- Ewha Authors
- 유영민
- SCOPUS Author ID
- 유영민
- Issue Date
- 2022
- Journal Title
- ORGANIC LETTERS
- ISSN
- 1523-7060
1523-7052
- Citation
- ORGANIC LETTERS vol. 24, no. 24, pp. 4479 - 4484
- Publisher
- AMER CHEMICAL SOC
- Indexed
- SCIE; SCOPUS
- Document Type
- Article
- Abstract
- Green-light-driven Fe-III(btz)(3) photocatalysis for the radical cationic [4+2] cycloaddition of terminal styrenes and nucleophilic dienes has been investigated. The Fe-MIC (mesoionic carbene) complex forms a ligand-to-metal charge-transfer transition state with relatively high excited-state reduction potentials that can selectively oxidize terminal styrene derivatives. Unique multisubstituted cyclohexenes and structurally complex biorelevant cyclohexenes were constructed, highlighting the usefulness of this mild and practical first-row transition metal complex system.
- DOI
- 10.1021/acs.orglett.2c01779
- Appears in Collections:
- 공과대학 > 화공신소재공학과 > Journal papers
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