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Acid Catalysis via Acid-Promoted Electron Transfer
- Title
- Acid Catalysis via Acid-Promoted Electron Transfer
- Authors
- Fukuzumi, Shunichi; Lee, Yong-Min; Nam, Wonwoo
- Ewha Authors
- 남원우; Shunichi Fukuzumi; 이용민
- SCOPUS Author ID
- 남원우; Shunichi Fukuzumi; 이용민
- Issue Date
- 2020
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- ISSN
- 0253-2964
1229-5949
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY vol. 41, no. 12, pp. 1217 - 1232
- Keywords
- Metal‐ oxygen complexes; Acid catalysis; Acid‐ promoted electron transfer; Proton‐ coupled electron transfer; Redox reaction
- Publisher
- WILEY-V C H VERLAG GMBH
- Indexed
- SCIE; SCOPUS; KCI
- Document Type
- Review
- Abstract
- This feature article focuses on acid catalysis in various redox reactions of not only organic compounds but also metal complexes, in particular metal-oxygen complexes via acid-promoted electron transfer (APET). On the other hand, proton-coupled electron transfer (PCET) has been extensively studied in relation with important biological PCET reactions such as O-2 reduction in respiration and water oxidation in photosynthesis. Because PCET is normally defined as simultaneous electron and proton transfer from the same substrate, acid-promoted electron transfer using external acids is called APET in this article. Various types of chemical transformations exhibiting acid catalysis via APET discussed in this article include C-C bond formation, C-H bond oxidation, aromatic hydroxylation, and oxygen atom transfer reactions such as sulfoxidation and epoxidation reactions.
- DOI
- 10.1002/bkcs.12124
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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