Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.contributor.author | Mian Guo | * |
dc.date.accessioned | 2021-02-18T16:30:44Z | - |
dc.date.available | 2021-02-18T16:30:44Z | - |
dc.date.issued | 2020 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.issn | 1520-5126 | * |
dc.identifier.other | OAK-28772 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/257021 | - |
dc.description.abstract | We report that Mn(III)-iodosylarene porphyrins, [Mn-III(Porp)((ArIO)-Ar-s)](+), are capable of activating the C-H bonds of hydrocarbons, including unactivated alkanes such as cyclohexane, with unprecedented reactivities, such as a low kinetic isotope effect, a saturation behavior of reaction rates, and no electronic effect of porphyrin ligands on the reactivities of [Mn-III(Porp)((ArIO)-Ar-s)](+). In oxygen atom transfer (OAT) reactions, the sulfoxidation of para-X-substituted thioanisoles by [Mn-III(Porp)((ArIO)-Ar-s)](+) affords a very unusual behavior in the Hammett plot with the saturation behavior of reaction rates and no electronic effect of porphyrin ligands on reactivities. The reactivities and mechanisms of [Mn-III(Porp)((ArIO)-Ar-s)](+) are then compared with those of the corresponding Mn-IV(Porp)(O) complex. The present study reports the first example of highly reactive Mn(III)-iodosylarene porphyrins with unprecedented reactivities in C-H bond activation and OAT reactions. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Unprecedented Reactivities of Highly Reactive Manganese(III)-Iodosylarene Porphyrins in Oxidation Reactions | * |
dc.type | Article | * |
dc.relation.issue | 47 | * |
dc.relation.volume | 142 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 19879 | * |
dc.relation.lastpage | 19884 | * |
dc.relation.journaltitle | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | * |
dc.identifier.doi | 10.1021/jacs.0c10159 | * |
dc.identifier.wosid | WOS:000595544800017 | * |
dc.author.google | Zhang, Lina | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Guo, Mian | * |
dc.author.google | Fukuzumi, Shunichi | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | Mian Guo(57193833363) | * |
dc.date.modifydate | 20240405124502 | * |