Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유영민 | * |
dc.date.accessioned | 2020-12-07T16:30:07Z | - |
dc.date.available | 2020-12-07T16:30:07Z | - |
dc.date.issued | 2020 | * |
dc.identifier.issn | 0022-3263 | * |
dc.identifier.issn | 1520-6904 | * |
dc.identifier.other | OAK-28140 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/255631 | - |
dc.description.abstract | The use of a visible light absorbing intermediate as a photosensitizer makes a chemical process simple and sustainable, obviating the need for the use of chemical additives. Herein, the formation of a photosensitizing disulfide in benzothiazole synthesis from 2-aminothiophenol and aldehydes was proposed and confirmed through in-depth mechanistic studies. A series of photophysical and electrochemical investigations revealed that an in situ-generated disulfide photosensitizes molecular oxygen to generate the key oxidants, singlet oxygen and superoxide anion, for the dehydrogenation step. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Benzothiazole Synthesis: Mechanistic Investigation of an In Situ-Generated Photosensitizing Disulfide | * |
dc.type | Article | * |
dc.relation.issue | 18 | * |
dc.relation.volume | 85 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 11835 | * |
dc.relation.lastpage | 11843 | * |
dc.relation.journaltitle | JOURNAL OF ORGANIC CHEMISTRY | * |
dc.identifier.doi | 10.1021/acs.joc.0c01598 | * |
dc.identifier.wosid | WOS:000574920600023 | * |
dc.author.google | Hwang, Ho Seong | * |
dc.author.google | Lee, Sumin | * |
dc.author.google | Han, Sung Su | * |
dc.author.google | Moon, Yu Kyung | * |
dc.author.google | You, Youngmin | * |
dc.author.google | Cho, Eun Jin | * |
dc.contributor.scopusid | 유영민(24759463600) | * |
dc.date.modifydate | 20240422132144 | * |