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Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst

Title
Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst
Authors
Moon, JisuMoon, Yu KyungPark, Do DamChoi, SukyungYou, YoungminCho, Eun Jin
Ewha Authors
유영민
SCOPUS Author ID
유영민scopus
Issue Date
2019
Journal Title
JOURNAL OF ORGANIC CHEMISTRY
ISSN
0022-3263JCR Link

1520-6904JCR Link
Citation
JOURNAL OF ORGANIC CHEMISTRY vol. 84, no. 20, pp. 12925 - 12932
Publisher
AMER CHEMICAL SOC
Indexed
SCI; SCIE; SCOPUS WOS
Document Type
Article
Abstract
Tri(9-anthryl)borane was successfully applied as an organophotocatalyst for the visible-light-induced trifluoromethylation of unactivated alkenes with CF3I. The mild reaction conditions tolerated a variety of functional groups, and the reaction could be extended to perfluoroalkylations with C3F7I and C4F9I. Mechanistic studies revealed that the photoredox catalysis involves an oxidative quenching pathway.
DOI
10.1021/acs.joc.9b01624
Appears in Collections:
엘텍공과대학 > 화학신소재공학전공 > Journal papers
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