Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유영민 | * |
dc.date.accessioned | 2019-11-22T16:30:11Z | - |
dc.date.available | 2019-11-22T16:30:11Z | - |
dc.date.issued | 2014 | * |
dc.identifier.issn | 1615-4150 | * |
dc.identifier.issn | 1615-4169 | * |
dc.identifier.other | OAK-25694 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/252187 | - |
dc.description.abstract | Difluoroalkylated aromatics are important structural motifs in pharmaceutical and agrochemical applications. Herein, we report their synthesis by a mild, efficient, and convenient method using visible light photoredox catalysis. A variety of unactivated aromatics were difluoroalkylated with ethyl 2-bromo-2,2-difluoroacetate (BrCF2CO2Et) in the presence of the triscyclometalated Ir complex fac-[Ir(ppy)(3)] under visible light irradiation at room temperature. It is shown that reaction outcomes containing the CF2CO2Et moiety can be converted to a variety of other CF2-containing aromatics, demonstrating the synthetic utility of the present method. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | aromatics | * |
dc.subject | difluoroalkylation | * |
dc.subject | heteroaromatics | * |
dc.subject | iridium | * |
dc.subject | visible light | * |
dc.title | Visible Light-Induced Aromatic Difluoroalkylation | * |
dc.type | Article | * |
dc.relation.issue | 13 | * |
dc.relation.volume | 356 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 2741 | * |
dc.relation.lastpage | 2748 | * |
dc.relation.journaltitle | ADVANCED SYNTHESIS & CATALYSIS | * |
dc.identifier.doi | 10.1002/adsc.201400542 | * |
dc.identifier.wosid | WOS:000342905600002 | * |
dc.author.google | Jung, Jaehun | * |
dc.author.google | Kim, Eunjin | * |
dc.author.google | You, Youngmin | * |
dc.author.google | Cho, Eun Jin | * |
dc.contributor.scopusid | 유영민(24759463600) | * |
dc.date.modifydate | 20240422132144 | * |