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Blue Electrofluorescence Resulting from Exergonic Harvesting of Triplet Excitons

Title
Blue Electrofluorescence Resulting from Exergonic Harvesting of Triplet Excitons
Authors
Yi, Seung YeonIhn, Soo-GhangSim, MyungsunKim, Jong SooKim, InkooChung, Yeon SookHuh, Dal HoKim, SunghanYou, Youngmin
Ewha Authors
유영민
SCOPUS Author ID
유영민scopus
Issue Date
2019
Journal Title
ADVANCED OPTICAL MATERIALS
ISSN
2195-1071JCR Link
Citation
ADVANCED OPTICAL MATERIALS vol. 7, no. 18
Keywords
El-Sayed ruleelectroluminescenceexciton harvestfluorescent moleculesintersystem crossing
Publisher
WILEY-V C H VERLAG GMBH
Indexed
SCIE; SCOPUS WOS
Document Type
Article
Abstract
Advances in electroluminescence demand the development of emissive molecules capable of utilizing all of the electrogenerated excitons. Here, a molecular strategy to harvest the excitons without relying on late transition metals or thermal activation is designed and evaluated. The key process deployed is an exergonic, El-Sayed rule-allowed reverse intersystem crossing (ES-rISC) from the triplet n-pi * transition state to the singlet pi-pi * transition state, followed by fluorescent decay of the latter. To demonstrate the strategy, a series of fluorescent molecules consisting of a 9,10-diphenylanthracene core and different carbonyl n-pi * units (SY compounds) is created. The compounds display a strong blue fluorescence emission with high photoluminescence quantum yields of up to 0.93. Multilayer organic electroluminescence devices containing the SY compounds exhibit maximum external quantum efficiencies greater than that obtained from a singlet-exciton-only control device. This improvement is due to their capacity to utilize triplet excitons for fluorescence emission. The studies demonstrate that exergonic ES-rISC can serve as a promising pathway for creating inexpensive and tractable organic dopants for high-efficiency electroluminescence.
DOI
10.1002/adom.201900630
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엘텍공과대학 > 화학신소재공학전공 > Journal papers
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