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자연과학대학
화학·나노과학전공
Journal papers
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Total synthesis of (+)-Valyldetoxinine and (-)-detoxin D1
Title
Total synthesis of (+)-Valyldetoxinine and (-)-detoxin D1
Authors
Li W.-R.
;
Han S.-Y.
;
Joullie M.M.
Ewha Authors
한소엽
SCOPUS Author ID
한소엽
Issue Date
1993
Journal Title
Tetrahedron
ISSN
0040-4020
Citation
Tetrahedron vol. 49, no. 4, pp. 785 - 802
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
The detoxin complex, metabolites produced by Streptomyces caespitosus var. detoxicus 7072 GC1, is a selective antagonist of the antibiotic blasticidin S. Two approaches toward the total synthesis of (+)-valyldetoxinine and (-)-detoxin D1 are described. These routes involve a 2,3-disubstituted pyrrolidine as a common intermediate and utilize glucose as the chiral precursor. © 1993.
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