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Syntheses and structures of Ag(I) compounds containing btp ligands
- Title
- Syntheses and structures of Ag(I) compounds containing btp ligands
- Authors
- Ryu J.Y.; Lee J.Y.; Choi S.H.; Hong S.J.; Kim C.; Kim Y.; Kim S.-J.
- Ewha Authors
- 김성진; 김영미
- SCOPUS Author ID
- 김성진; 김영미
- Issue Date
- 2005
- Journal Title
- Inorganica Chimica Acta
- ISSN
- 0020-1693
- Citation
- Inorganica Chimica Acta vol. 358, no. 12, pp. 3398 - 3406
- Indexed
- SCI; SCIE; SCOPUS
- Document Type
- Article
- Abstract
- Four new Ag(I) complexes with three different modes of structures were obtained by varying the counteranions (ClO4-for1,PF6-for2,CF3SO3-(OTf-)for3, andCF3CO2-for4), and their structures characterized by single-crystal X-ray diffraction analysis. Compounds 1, 2, and 3 crystalize in the C-centered monoclinic space group C2/m. Compound 4 crystalizes in the monoclinic space group P21/c. The crystal structures of these complexes show that the complexes 1, 2, and 3 form ligand-supported dinuclear rings, and the dinuclear units of 1 and 3 are further linked by anions to form one-dimensional polymer, while the complex 4 forms an one-dimensional zigzag chain. The structural differences between 1, 2, 3, and 4 show the influences of the counteranions on the structures of the complexes. © 2005 Published by Elsevier B.V.
- DOI
- 10.1016/j.ica.2005.04.004
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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