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A Mononuclear Nonheme Iron(V)-Imido Complex

Title
A Mononuclear Nonheme Iron(V)-Imido Complex
Authors
Hong, SeungwooSutherlin, Kyle D.Vardhaman, Anil KumarYan, James J.Park, SoraLee, Yong-MinJang, SoojeongLu, XiaoyanOhta, TakehiroOgura, TakashiSolomon, Edward I.Nam, Wonwoo
Ewha Authors
남원우이용민
SCOPUS Author ID
남원우scopus
Issue Date
2017
Journal Title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN
0002-7863JCR Link
Citation
vol. 139, no. 26, pp. 8800 - 8803
Publisher
AMER CHEMICAL SOC
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
DOI
10.1021/jacs.7b04695
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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