View : 17 Download: 0

Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(IV)-oxo complexes

Title
Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(IV)-oxo complexes
Authors
Lee, Yong-MinYoo, MiYoon, HeejungLi, Xiao-XiNam, WonwooFukuzumi, Shunichi
Ewha Authors
남원우Shunichi Fukuzumi
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus
Issue Date
2017
Journal Title
CHEMICAL COMMUNICATIONS
ISSN
1359-7345JCR Link1364-548XJCR Link
Citation
vol. 53, no. 67, pp. 9352 - 9355
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCI; SCIE; SCOPUS WOS
Abstract
Direct oxygen atom transfer from a nonheme Mn(IV)-oxo complex, [(Bn-TPEN)Mn-IV(O)](2+), to triphenylphosphine (Ph3P) derivatives occurs with a significant steric effect resulting from the ortho-substituents on the phenyl group of the Ph3P derivatives, whereas the phosphine oxygenation by a Mn(IV)-oxo complex in the presence of HOTf occurs via an electron transfer mechanism without the substrate-steric effect.
DOI
10.1039/c7cc04035k
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE