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Transition metal-catalyzed site- and regio-divergent C-H bond functionalization

Title
Transition metal-catalyzed site- and regio-divergent C-H bond functionalization
Authors
Ping L.Chung D.S.Bouffard J.Lee S.-G.
Ewha Authors
이상기Jean Bouffard
SCOPUS Author ID
이상기scopus; Jean Bouffardscopus
Issue Date
2017
Journal Title
Chemical Society Reviews
ISSN
0306-0012JCR Link
Citation
vol. 46, no. 14, pp. 4299 - 4328
Publisher
Royal Society of Chemistry
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Recent advances in transition metal-catalyzed C-H bond functionalization have profoundly impacted synthetic strategy. Since organic substrates typically contain several chemically distinct C-H bonds, controlling the regioselectivity of C-H bond functionalization is imperative to harness its full potential. Moreover, the ability to alter reaction pathways to selectively functionalize different C-H bonds in a substrate represents a greater opportunity and challenge. The choice of catalysts, ligands, solvents, and even more subtle variations of the reaction conditions have been shown to allow the formation of regioisomeric C-H functionalization products starting from the same precursors. This review describes recent advances in transition metal-catalyzed divergent C-H bond functionalization that highlight its potential in organic synthesis. © 2017 The Royal Society of Chemistry.
DOI
10.1039/c7cs00064b
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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