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A Mononuclear Nonheme Iron(V)-Imido Complex

Title
A Mononuclear Nonheme Iron(V)-Imido Complex
Authors
Hong S.Sutherlin K.D.Vardhaman A.K.Yan J.J.Park S.Lee Y.-M.Jang S.Lu X.Ohta T.Ogura T.Solomon E.I.Nam W.
Ewha Authors
남원우이용민
SCOPUS Author ID
남원우scopus
Issue Date
2017
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 139, no. 26, pp. 8800 - 8803
Publisher
American Chemical Society
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) Å, and an Fe - N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions. © 2017 American Chemical Society.
DOI
10.1021/jacs.7b04695
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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