Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 유영민 | * |
dc.date.accessioned | 2017-03-09T01:03:56Z | - |
dc.date.available | 2017-03-09T01:03:56Z | - |
dc.date.issued | 2017 | * |
dc.identifier.issn | 0743-7463 | * |
dc.identifier.other | OAK-20161 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/234712 | - |
dc.description.abstract | Halogenated organic compounds are important anthropogenic chemicals widely used in chemical industry, biology, and pharmacology; however, the persistence and inertness of organic halides cause human health problems and replacement of halogen atoms with organic halides has been considerable environmental pollution. Thus, the elimination or considered a central task in synthetic chemistry. In dehalogenation reactions, the consecutive single-electron transfer from reducing agents generates the radical and corresponding carbanion and thus removes the halogen atom as the leaving group. Herein, we report a new strategy for an efficient chemoselective hydrodehalogenation through the formation of stable carbanion intermediates, which are simply achieved by using highly mobile two-dimensional electrons of inorganic electride [Ca2N](+)center dot e(-) with effective electron transfer ability. The consecutive single-electron transfer from inorganic electride [Ca2N](+)center dot e(-) stabilized free carbanions, which is a key step in achieving the selective reaction. Furthermore, a determinant more important than leaving group ability is the stability control of free carbanions according to the s character determined by the backbone structure. We anticipate that this approach may provide new insight into selective chemical formation, including hydrodehalogenation. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Chemoselective Hydrodehalogenation of Organic Halides Utilizing Two-Dimensional Anionic Electrons of Inorganic Electride [Ca2N](+)center dot e(-) | * |
dc.type | Article | * |
dc.relation.issue | 4 | * |
dc.relation.volume | 33 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 954 | * |
dc.relation.lastpage | 958 | * |
dc.relation.journaltitle | LANGMUIR | * |
dc.identifier.doi | 10.1021/acs.langmuir.6b04152 | * |
dc.identifier.wosid | WOS:000393269700014 | * |
dc.identifier.scopusid | 2-s2.0-85011019632 | * |
dc.author.google | Kim, Ye Ji | * |
dc.author.google | Kim, Sun Min | * |
dc.author.google | Yu, Chunghyeon | * |
dc.author.google | Yoo, YoungMin | * |
dc.author.google | Cho, Eun Jin | * |
dc.author.google | Yang, Jung Woon | * |
dc.author.google | Kim, Sung Wng | * |
dc.contributor.scopusid | 유영민(24759463600) | * |
dc.date.modifydate | 20240422132144 | * |