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A family of octahedral rhenium cluster complexes [Re6Q 8(H2O)n(OH)6-n]n-4 (Q = S, Se; n = 0-6): Structural and pH-dependent spectroscopic studies

Title
A family of octahedral rhenium cluster complexes [Re6Q 8(H2O)n(OH)6-n]n-4 (Q = S, Se; n = 0-6): Structural and pH-dependent spectroscopic studies
Authors
Brylev K.A.Mironov Y.V.Yarovoi S.S.Naumov N.G.Fedorov V.E.Kim S.-J.Kitamura N.Kuwahara Y.Yamada K.Ishizaka S.Sasaki Y.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2007
Journal Title
Inorganic Chemistry
ISSN
0020-1669JCR Link
Citation
vol. 46, no. 18, pp. 7414 - 7422
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The conversions of hexahydroxo rhenium cluster complexes [Re 6Q8(OH)6]4- (Q = S, Se) in aqueous solutions in a wide pH range were investigated by chemical methods and spectroscopic measurements. Dependences of the spectroscopic and excited-state properties of the solutions on pH have been studied in detail. It has been found that a pH decrease of aqueous solutions of the potassium salts K 4[Re6Q8(OH)6]·8H 2O (Q = S, Se) results in the formation of aquahydroxo and hexaaqua cluster complexes with the general formula [Re6Q8(H 2O)n(OH)6-n]n-4 that could be considered as a result of the protonation of the terminal OH- ligands in the hexahydroxo complexes. The compounds K2[Re6S 8(H2O)2(OH)4]·2H 2O (1), [Re6S8(H2O) 4(OH)2]·12H2O (2), [Re6S 8(H2O)6][Re6S6Br 8]·10H2O (3), and [Re6Se 8(H2O)4(OH)2] (4) have been isolated and characterized by X-ray single-crystal diffraction and elemental analyses and infrared (IR) spectroscopy. In crystal structures of the aquahydroxo complexes, the cluster units are connected to each other by an extensive system of very strong hydrogen bonds between terminal ligands. © 2007 American Chemical Society.
DOI
10.1021/ic7005265
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자연과학대학 > 화학·나노과학전공 > Journal papers
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